"The girl is going to the school even though she wants to sleep."
Translation:Девочка идёт в школу, хотя и хочет спать.
If you use хотя и instead of хотя here, you can either remove the pronoun or put it between хотя and и. И doesn't replace the pronoun, it's just a part of the conjunction. Your answer isn't correct here though. It means that "the girl is going to (the?) school, even though she wants to sleep, too".