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dobrze is an adverb, in English "well" or "fine." How are you? Dobrze. I am well.
Dobre is a gender-neuter adjective, in English "good," but used with a gender-neuter noun, such as dobre miasto, "good city," or a plural noun, such as dobre miasta, "good cities," but not a plural noun that includes at least one male person, which uses dobrzy.