I answered Ezek ablakok, pedig azok székek, thinking "while those are chairs." I understand how azok pedig can work 'those, meanwhile, are chairs,' or close to that, though can pedig azok also work in that order?
Not really. With that word order, "pedig" means something more like "despite the fact that...". I can imagine someone complaining "How can these be tables if those are chairs? How is this possible?" :D