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For feminine words in the nominative and accusative cases (nominative = subject [as "Frau" in "Eine Frau isst eine Orange" - the thing that does the verb], accusative = direct object [as "Orange" in "Eine Frau isst eine Orange" - the thing that DIRECTLY receives the doing of the verb]), you append an "e" to words like "ein" "kein" "mein" "dein" adjectives ("gut", "schlecht") etc.
Grammatical gender doesn't always correspond to real gender. The word came from "die Magd", which means "the maiden" (it's an old word now, and has medieval connotations), and it took the diminutive ending of -chen to get a meaning of "the girl" by becoming "das Mädchen". All words that take the diminutive ending of -chen are neutral. So the original word is feminine, but because this is a -chen diminutive of the original word, it is neuter regardless of the original word's gender.
The following usually, but for some of them not always, are feminine: -a, -age, -anz, -ei, -enz, -heit, -ie, -ik, -in, -ion, -itis, -keit, -schaft, -sion, -sis, -tät, -tion, -ung, -ur, numerals, female humans and animals, named aeroplanes, motorbikes and ships, native German names for rivers, nouns derived from verbs that end in -t.
The following usually, but for some of them not always, are masculine: -ast, -ich, -ig, -ismus, -ling, -ner, -or, alcoholic and plant-based drinks, directions and weather types, makes of car, male human and animals, named mountains and mountain ranges, nouns from strong verbs without a suffix, rivers outside Germany, rocks and minerals, seasons, months, days of the week, units of money.
Moreover, -er, -en and -el are 60% of the time masculine, and -e is 90% of the time feminine.
Masculine words take "der" as a definite article, and feminine "die" ( although this does change according to case when in actual use: http://german.about.com/library/blcase_sum.htm ).
Adia_Cheng made me realise that it's a bit like "ch" sound in German, except more back: http://www.germanculture.com.ua/library/howto/htpronounce.htm
One uses the -en ending for "die jungen Frauen", which is "the young women". (definite plural) "the young woman" would be "die junge Frau" with only an -e ending. (definite singular) It's simple with masculine, feminine, and neuter definite forms in the nominative case, as they just take an -e ending for adjectives ("der kleine Hund", "die kleine Katze", "das kleine Kaninchen"), but the plural definite form in the nominative case takes an -en ending for adjectives ("die kleinen Hunde").
You can check the following link for the appropriate adjective endings in the nominative case: http://german.about.com/library/weekly/aa030298.htm
"Eine" means "one"/"a"/"an", and it is used for feminine nouns (the -e ending is also for plural, but there's no "eine" for plural of course). Masculine and neuter nouns rather take "ein". These endings apply to the nominative case (subject of clause).
If you want the number one, it is "eins".
"She is a woman" = "Sie ist eine Frau" and "I am a man" = "Ich bin ein Mann"
"die Frau" is a feminine noun, so it takes "eine", and "der Mann" is a masculine noun, so it takes "ein". This applies to nominative case, which is the subject of a clause. One has to learn the gender for each noun.