No. We usually say "andares". We say "piso" when you are already inside the building or to refer to its inside, ex: consultório do dentista é no segundo piso/andar. Moro no quinto piso/andar. Inside the building you may also find signs indicating where you are using the word piso: primeiro/segundo/terceiro.... piso/andar. Hope you got it :)

I think duo prefers more literal translations.... the translation for building is edifício, prédio . In my region we normally use prédio ;)